{"id":29317,"date":"2024-03-12T04:24:35","date_gmt":"2024-03-12T05:24:35","guid":{"rendered":"https:\/\/express24.ir\/d\/product\/%d9%85%d9%82%d8%a7%d9%84%d9%87-%d9%86%d9%85%d8%a7%db%8c%d8%b4%db%8c-%d8%a7%d8%b2-%d8%ac%d9%81%d8%aa-%d9%87%d8%a7%db%8c-%d8%a2%d9%86%d8%aa%d8%a7%da%af%d9%88%d9%86%db%8c%d8%b3%d8%aa%db%8c-%d8%a8%d9%87\/"},"modified":"2024-03-12T04:24:36","modified_gmt":"2024-03-12T05:24:36","slug":"%d9%85%d9%82%d8%a7%d9%84%d9%87-%d9%86%d9%85%d8%a7%db%8c%d8%b4%db%8c-%d8%a7%d8%b2-%d8%ac%d9%81%d8%aa-%d9%87%d8%a7%db%8c-%d8%a2%d9%86%d8%aa%d8%a7%da%af%d9%88%d9%86%db%8c%d8%b3%d8%aa%db%8c-%d8%a8%d9%87","status":"publish","type":"product","link":"https:\/\/express24.ir\/d\/product\/%d9%85%d9%82%d8%a7%d9%84%d9%87-%d9%86%d9%85%d8%a7%db%8c%d8%b4%db%8c-%d8%a7%d8%b2-%d8%ac%d9%81%d8%aa-%d9%87%d8%a7%db%8c-%d8%a2%d9%86%d8%aa%d8%a7%da%af%d9%88%d9%86%db%8c%d8%b3%d8%aa%db%8c-%d8%a8%d9%87\/","title":{"rendered":"\u0645\u0642\u0627\u0644\u0647 \u0646\u0645\u0627\u06cc\u0634\u06cc \u0627\u0632 \u062c\u0641\u062a \u0647\u0627\u06cc \u0622\u0646\u062a\u0627\u06af\u0648\u0646\u06cc\u0633\u062a\u06cc \u0628\u0647 \u0639\u0646\u0648\u0627\u0646 \u0645\u0633\u06cc\u0631\u06cc \u0628\u0647 \u0633\u0645\u062a \u062a\u0631\u06a9\u06cc\u0628\u0627\u062a \u0633\u0647 \u062a\u0627\u06cc\u06cc \u0628\u0627 \u0627\u0628\u0639\u0627\u062f \u06a9\u0645"},"content":{"rendered":"\n\n\n\n\n\n\n\n\n\n\n
\u0639\u0646\u0648\u0627\u0646 \u0645\u0642\u0627\u0644\u0647 \u0628\u0647 \u0627\u0646\u06af\u0644\u06cc\u0633\u06cc <\/td>\nLa$_4$Co$_4$X (X = Pb, Bi, Sb): a demonstration of antagonistic pairs as a route to quasi-low dimensional ternary compounds<\/td>\n<\/tr>\n
\u0639\u0646\u0648\u0627\u0646 \u0645\u0642\u0627\u0644\u0647 \u0628\u0647 \u0641\u0627\u0631\u0633\u06cc <\/td>\n\u0645\u0642\u0627\u0644\u0647 \u0646\u0645\u0627\u06cc\u0634\u06cc \u0627\u0632 \u062c\u0641\u062a \u0647\u0627\u06cc \u0622\u0646\u062a\u0627\u06af\u0648\u0646\u06cc\u0633\u062a\u06cc \u0628\u0647 \u0639\u0646\u0648\u0627\u0646 \u0645\u0633\u06cc\u0631\u06cc \u0628\u0647 \u0633\u0645\u062a \u062a\u0631\u06a9\u06cc\u0628\u0627\u062a \u0633\u0647 \u062a\u0627\u06cc\u06cc \u0628\u0627 \u0627\u0628\u0639\u0627\u062f \u06a9\u0645<\/td>\n<\/tr>\n
\u0646\u0648\u06cc\u0633\u0646\u062f\u06af\u0627\u0646 <\/td>\nTyler J. Slade, Nao Furukawa, Matthew Dygert, Siham Mohamed, Atreyee Das, Weiyi Xia, Cai-Zhuang Wang, Sergey L. Budko, Paul C. Canfield<\/td>\n<\/tr>\n
\u0632\u0628\u0627\u0646 \u0645\u0642\u0627\u0644\u0647 <\/td>\n\u0627\u0646\u06af\u0644\u06cc\u0633\u06cc<\/td>\n<\/tr>\n
\u0641\u0631\u0645\u062a \u0645\u0642\u0627\u0644\u0647: <\/td>\nPDF<\/td>\n<\/tr>\n
\u062a\u0639\u062f\u0627\u062f \u0635\u0641\u062d\u0627\u062a<\/td>\n25<\/td>\n<\/tr>\n
\u062f\u0633\u062a\u0647 \u0628\u0646\u062f\u06cc \u0645\u0648\u0636\u0648\u0639\u0627\u062a <\/td>\nMaterials Science,\u0639\u0644\u0645 \u0645\u0648\u0627\u062f,<\/td>\n<\/tr>\n
\u062a\u0648\u0636\u06cc\u062d\u0627\u062a <\/td>\nSubmitted 29 February, 2024; originally announced March 2024.<\/td>\n<\/tr>\n
\u062a\u0648\u0636\u06cc\u062d\u0627\u062a \u0628\u0647 \u0641\u0627\u0631\u0633\u06cc <\/td>\n\u0627\u0631\u0633\u0627\u0644 \u0634\u062f\u0647 29 \u0641\u0648\u0631\u06cc\u0647 2024 \u061b\u062f\u0631 \u0627\u0628\u062a\u062f\u0627 \u0645\u0627\u0631\u0633 2024 \u0627\u0639\u0644\u0627\u0645 \u0634\u062f.<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u0686\u06a9\u06cc\u062f\u0647<\/h2>\n

We outline how pairs of strongly immiscible elements, referred to here as antagonistic pairs, can be used to synthesize ternary compounds with quasi-reduced dimensional motifs. By identifying third elements that are compatible with a given antagonistic pair, ternary compounds can be formed in which the third element segregates the immiscible atoms into spatially separated substructures. Quasi-low dimensional structural units are a natural consequence of the immiscible atoms seeking to avoid contact in the solid-state. As proof of principle, we present the discovery and physical properties of La$_4$Co$_4$X (X = Pb, Bi, Sb), a new family of intermetallics based on the antagonistic pairs Co-Pb and Co-Bi. La$_4$Co$_4$X adopts a new orthorhombic crystal structure (space group Pbam) containing quasi-2D Co slabs and La-X layers that stack along the a-axis. Consistent with our proposal, the La atoms separate the Co and X substructures, ensuring there are no direct contacts between immiscible atoms. Within the Co slabs, the atoms occupy the vertices of corner sharing tetrahedra and triangles, and this motif produces flat electronic bands near the Fermi level that favor magnetism. The Co is moment bearing in La$_4$Co$_4$X, and we show that whereas La$_4$Co$_4$Pb behaves as a three dimensional antiferromagnet with T$_N$ = 220 K, La$_4$Co$_4$Bi and La$_4$Co$_4$Sb have behavior consistent with low dimensional magnetic coupling and ordering, with T$_N$ = 153 K and 143 K respectively. In addition to the Pb, Bi, and Sb based La$_4$Co$_4$X compounds, we were likely able to produce an analogous La$_4$Co$_4$Sn in polycrystalline form, although we were unable to isolate single crystals. We anticipate that using mutually compatible third elements with an antagonistic pair represents a generalizable design principle for discovering new materials and structure types containing low-dimensional substructures.<\/p>\n

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\u0627\u0644\u06a9\u062a\u0631\u0648\u0646\u06cc\u06a9\u06cc \u0645\u0633\u0637\u062d \u062f\u0631 \u0646\u0632\u062f\u06cc\u06a9\u06cc \u0633\u0637\u062d \u0641\u0631\u0645\u06cc \u062a\u0648\u0644\u06cc\u062f \u0645\u06cc \u06a9\u0646\u062f \u06a9\u0647 \u0628\u0647 \u0646\u0641\u0639 \u0645\u063a\u0646\u0627\u0637\u06cc\u0633 \u0627\u0633\u062a.\u0627\u06cc\u0646 \u0634\u0631\u06a9\u062a \u0644\u062d\u0638\u0647 \u0628\u0647 \u0644\u062d\u0638\u0647 \u062f\u0631 LA $ _4 $ $ _4 $ x \u0627\u0633\u062a \u060c \u0648 \u0645\u0627 \u0646\u0634\u0627\u0646 \u0645\u06cc \u062f\u0647\u06cc\u0645 \u06a9\u0647 \u062f\u0631 \u062d\u0627\u0644\u06cc \u06a9\u0647 LA $ _4 $ $ $ _4 $ PB \u0628\u0647 \u0639\u0646\u0648\u0627\u0646 \u06cc\u06a9 \u0622\u0646\u062a\u06cc \u0641\u0631\u0648\u0645\u06af\u0646\u062a \u0633\u0647 \u0628\u0639\u062f\u06cc \u0628\u0627 T $ _n $ = 220 K \u060c LA $ _4 $ CO \u0631\u0641\u062a\u0627\u0631 \u0645\u06cc \u06a9\u0646\u062f.$ _4 $ bi \u0648 la $ _4 $ $ _4 $ sb 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\u062f\u0647\u062f.<\/p>\n\r\n\r\n\t\r\n\t
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\r\n\t09395106248\r\n\t\t\r\n\t\t\r\n\t

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    \r\n\t\t
  • \r\n\t\t\u0642\u06cc\u0645\u062a \u0647\u0631 \u0635\u0641\u062d\u0647 \u062a\u0631\u062c\u0645\u0647 \u062f\u0631 \u062d\u0627\u0644 \u062d\u0627\u0636\u0631 40 \u0647\u0632\u0627\u0631 \u062a\u0648\u0645\u0627\u0646 \u0645\u06cc \u0628\u0627\u0634\u062f. \r\n\t\t<\/li>\r\n\t\t
  • \r\n\t\t\u062a\u062d\u0648\u06cc\u0644 \u0645\u0642\u0627\u0644\u0647 \u062a\u0631\u062c\u0645\u0647 \u0634\u062f\u0647 \u0628\u0647 \u0635\u0648\u0631\u062a \u0641\u0627\u06cc\u0644 \u0648\u0631\u062f \u0645\u06cc \u0628\u0627\u0634\u062f.\r\n\t\t<\/li>\r\n\t\t
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  • \r\n\t\t\u06a9\u06cc\u0641\u06cc\u062a \u062a\u0631\u062c\u0645\u0647 \u0628\u0633\u06cc\u0627\u0631 \u0628\u0627\u0644\u0627 \u0645\u06cc \u0628\u0627\u0634\u062f. \u0645\u0642\u0627\u0644\u0647 \u0641\u0642\u0637 \u062a\u0648\u0633\u0637 \u0645\u062a\u0631\u062c\u0645\u06cc\u0646 \u0628\u0627 \u0645\u062f\u0631\u06a9 \u062f\u0627\u0646\u0634\u06af\u0627\u0647\u06cc \u0645\u062a\u0631\u062c\u0645\u06cc \u062a\u0631\u062c\u0645\u0647 \u0645\u06cc\u200c\u0634\u0648\u062f.\r\n\t\t<\/li>\r\n\t\t
  • \r\n\t\t\u06a9\u0644\u06cc\u0647 \u062c\u062f\u0627\u0648\u0644 \u0648 \u0641\u0631\u0645\u0648\u0644 \u0647\u0627 \u0646\u06cc\u0632 \u062f\u0631 \u0641\u0627\u06cc\u0644 \u062a\u062d\u0648\u06cc\u0644\u06cc \u0648\u0631\u062f \u062f\u0631\u062c \u0645\u06cc\u200c\u0634\u0648\u0646\u062f.\r\n\t\t<\/li>\r\n\t<\/td>\r\n\t\r\n\t\r\n<\/tr>\r\n<\/table>\r\n\r\n\r\n\n","protected":false},"excerpt":{"rendered":"

    \u0639\u0646\u0648\u0627\u0646 \u0645\u0642\u0627\u0644\u0647 \u0628\u0647 \u0627\u0646\u06af\u0644\u06cc\u0633\u06cc La$_4$Co$_4$X (X = Pb, Bi, Sb): a demonstration of antagonistic pairs as a route to quasi-low […]<\/p>\n","protected":false},"featured_media":27,"comment_status":"open","ping_status":"closed","template":"","meta":{"pmpro_default_level":"","site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}}},"product_cat":[15,21],"product_tag":[335,382],"class_list":{"0":"post-29317","1":"product","2":"type-product","3":"status-publish","4":"has-post-thumbnail","6":"product_cat-15","7":"product_cat-21","8":"product_tag-materials-science","9":"product_tag-382","10":"pmpro-has-access","11":"desktop-align-left","12":"tablet-align-left","13":"mobile-align-left","15":"first","16":"instock","17":"shipping-taxable","18":"purchasable","19":"product-type-variable"},"yoast_head":"\n\u0645\u0642\u0627\u0644\u0647 \u0646\u0645\u0627\u06cc\u0634\u06cc \u0627\u0632 \u062c\u0641\u062a \u0647\u0627\u06cc \u0622\u0646\u062a\u0627\u06af\u0648\u0646\u06cc\u0633\u062a\u06cc \u0628\u0647 \u0639\u0646\u0648\u0627\u0646 \u0645\u0633\u06cc\u0631\u06cc \u0628\u0647 \u0633\u0645\u062a \u062a\u0631\u06a9\u06cc\u0628\u0627\u062a \u0633\u0647 \u062a\u0627\u06cc\u06cc \u0628\u0627 \u0627\u0628\u0639\u0627\u062f \u06a9\u0645 - 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